Zuckerberg will instead send his Chief Technology Officer Mike Schroepfer or Chief Product Officer Chris Cox to appear before parliament's Digital, Culture, Media and Sport committee.
British MPs, however, renewed their demand to interview Zuckerberg personally over a data privacy row.
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In a letter published by the committee on Tuesday, a senior British Facebook executive offered to send Schroepfer or chief product officer Chris Cox to London next month.
“We’d be very happy to invite Mr Cox to give evidence,” Collins said at the start of a committee hearing on Tuesday.
"However we would still like to hear from Mr Zuckerberg as well.
"We will seek to clarify with Facebook whether he is available to give evidence or not, because that wasn't clear from our correspondence, and if he is available to give evidence then we would be happy to do that either in person or via video link if that would be more convenient for him.”
In the letter to Collins, Rebecca Stimson, head of public policy for Facebook UK, wrote: “Facebook fully recognizes the level of public and Parliamentary interest in these issues and support your belief that these issues must be addressed at the most senior levels of the company by those in an authoritative position.”
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