The United States and its allies have told the Syrian opposition to expect military action soon against President Bashar al-Assad's forces, which were blamed for last week's chemical weapons attacks.
Brent has gained 4% and the US benchmark 3% so far this week on worries tensions in Syria could engulf major crude producers in the West Asia, which pumps a third of the world's oil.
"Assuming they (the Western powers) take action, it's likely for the risk premium to be built in for quite a while," said Ric Spooner, chief market analyst at CMC Markets in Sydney.
Brent earlier jumped to a 6-month high of $117.34 a barrel and was at $116.07, up $1.71, at 0759 GMT. US crude rose $1.16 to $110.17, after hitting an intraday peak of $112.24 - its highest since May 2011.
The risk premium could vary from $10 to $25, Spooner said, adding that if the situation worsens Brent could rise to $119-$126 and US crude could move towards $114-$115.
"Given that the end result of any military action is likely to be drawn out and messy, the doors for Brent prices towards $120 have now been opened," analysts at Energy Aspects said in a note.
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"While the events in Syria have little impact on oil prices in isolation, the potential impacts flowing through to the rest of the region are high while sectarian violence continues in Iraq and supplies from Nigeria, Libya and Sudan continue to disappoint," ANZ analysts wrote in a note.
Oil could also get a boost if the US Federal Reserve decides to start paring back its bond purchases later than the anticipated September timeline.
"Another potential outcome from Syria is that if it does deteriorate, it could make the Fed less likely to act in September," CMC's Spooner said. "It's another general supportive factor for commodities, including oil."
Investors are now waiting for weekly oil inventory data from the United States later in the day for clues on demand in the world's top consumer.
US crude stocks rose last week while gasoline inventories declined and distillate stocks increased, data from industry group the American Petroleum Institute showed.