The two were identified as Gita Kunjami (25) alias Jamuna of Badigata in Kalimela area and Saita Pangi (22) of Chitrakonda area, Deputy Superintendent of Police P K Bagh said.
While Jamuna had been an area committee member of Kalimela Maoist Dalam since 2007, Saita had joined the rebel outfit in 2012, he said, adding that both the women had been imparted training in handling of different weapons.
The two were also engaged by the rebels in various programmes and cultural activities as part of their strategy to woo the youths, police sources said.
However, the two women decided to quit the organisation and return to the social mainstream as they were disillusioned due to torture and harassment by senior ultras.