The "Skyfall" hitmaker will perform a song from her third album "25", which broke first-week sales records in multiple countries including the US and the UK, reported AceShowbiz.
Nominated for five Grammys this year, the 28-year-old songstress is up for Album of the Year and Best Pop Vocal Album for "25".
She is also nominated for Record of the Year, Song of the Year and Best Pop Solo Performance for "Hello".
Last year, a musical mishap interrupted the singer's Grammys performance as her microphone repeatedly hit the strings of the on-stage piano.
James Corden will host the star-studded affair that will take place at Staples Center, here on February 12.