This is the maiden visit of any Indian President to Ghana and Ivory coast whereas to Namibia, such a visit comes after two decades.
On his arrival here for a two-day visit, he was received at the airport by Ghana's Vice-President Kwesi Bekoe Amissah- Arthur.
Even though Mukherjee has toured number of countries in the continent, he is visiting these countries for the first time in his long political career.
The President is accompanied by Minister of State for the PMO Jitendra Singh and BJP MPs - SS Ahluwalia and Mansukh L Mandaviya.
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"As you know this is the part of the Outreach to Africa, which was kicked off with the visit to Morocco and Tunisia by Vice President... Then the President has taken on the responsibility of these three country visits," he said.
The President will be given a ceremonial welcome tomorrow followed by delegation level talks at President's House which is called Flag Staff House.
The imposing building has an Indian touch as it is constructed by an Indian company Shapoorji Pallonji.
In the delegation level talks, there are likely to be discussions on agreements on visa waiver and about two Line of Credits could also be deliberated.
"Investment in Ghana is substantial, nearly three billion
"Ghana's main trade consists of gold imports, it's nearly 80 per cent of total trade. Ghanaian gold is in great demand in India," Sinha said.
Mukherjee will be addressing a joint business forum meeting here which has been organised by business groups from India and Ghana.
Ghana has a very prosperous Indian-origin community, roughly around 10,000, of which 7,000 have Indian passports with some families arriving here as early as 1920's.
Mukherjee will also be visiting the India-Ghana Kofi Annan Center of ICT Excellence, set up by India, and will meet its faculty and alumni. The Institute was set up by India few years ago.
"I am told that it is working very well. So it will be a great opportunity to go there and see whether we could contribute something else or help in up gradation," he said.