The face-to-face conversation will be conducted on a unique Google application called 'Hangout', a release issued here said.
Ajay, who is currently shooting in Hyderabad for Sajid Khan's upcoming film 'Himmatwala', will fly to Ahmedabad on August 31 to host the session with the leader.
This is the first time an Indian political leader would be using the forum to engage with people across the world, the release said.
Other leaders who have held Google 'Hangout' sessions include US President Barack Obama and Australian Prime Minister Julia Gilliard.