The award ceremony, hosted by Ellen DeGeneres, will air on Sunday, March 2.
Hathaway, 31, won last year's Supporting Actress Oscar for her performance in 'Les Miserables'.
She was previously nominated for her leading role in the 2008 film 'Rachel Getting Married'.
Hathaway, who made her feature film debut in 2001's 'The Princess Diaries', has starred in films including 'Ella Enchanted', 'The Devil Wears Prada' and 'The Dark Knight Rises.