The 21-year-old singer is just the latest to perform during the NBA's showcase of the stars, following in the footsteps of Mariah Carey, Rihanna and Beyonce, reported Rolling Stones magazine.
Grande is the first artist confirmed for All-Star Weekend, which features events at both at the Garden and Brooklyn's Barclays Center.
The league also revealed that Nico & Vinz will perform during the official All-Star Game practice session at MSG on February 14.