The MoU has been signed days after the state government announced its garments and apparel policy, 2017, the company said in a release here.
The "mega apparel facility" will be a "first-of-its-kind" which will employ more than 10,000 people, it said.
The government's policy envisages achieving textile-to-garment value chain of 5 Fs -- farm, fibre, fabric, fashion, and foreign markets, said the release.
The park is expected to commence commercial production in the fourth quarter of 2018-19 financial year and will produce over 24 million garments once it is fully operational, the company said.
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"We plan to commence commercial production in the fourth quarter of 2018 and we plan to create 10,000 jobs, a majority of which will be women.
"We are excited to support the Gujarat Apparel Policy which aims to create 1 lakh jobs in the state," the release quoted Kulin Lalbhai as saying.
Arvind Limited is one of India's largest integrated textile and apparel company which has registered a turnover of nearly USD 1.5 billion in FY 2016-17.