Australia outplayed Argentina 5-1 in the semifinal at the Kyocera Stadium here today, to earn a title encounter with Netherlands, who defeated England 1-0.
Australia have won the World Cup twice (in 1986 and 2010), while Netherlands have inscribed their name on the trophy three times - in 1973, 1990 and 1998.
Before the men's final on Sunday, the same two nations will clash in the women's final tomorrow.
Netherlands are the only nation to have won both the men and women's World Cups in the same year (in 1990) but in separate tournaments.
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Jeremy Hayward converted two penalty corners for the rampant Australian team that stamped its supremacy against first-time semifinalists Argentina.
Four of the Australian goals came through penalty corner conversions. Before Hayward came into the frame, Kieran Govers opened Australia's scoring with low penalty corner shot into the boards in the fourth minute.
Hayward then duly capitalised on the next penalty corner in the 22nd minute.
Chris Ciriello (49th minute) and Hayward (55th) converted successive penalty corners to give Australia a five-goal lead before Argentina pulled a goal back in the 58th minute through Gonzalo Piellat.
Chasing their fourth World Cup title, hosts Netherlands rode on a penalty corner conversion by Mike van der Weerden in the 31st minute to overcome the dogged England defence.
Van der Weerden sent a drag flick, on Netherlands' second penalty corner, soaring into the net to the left of goalkeeper George Pinner, who warded off many raids by the rampant Dutch attack but was beaten this time.
England were constantly under pressure from the Dutch strikers, but managed to build some raids into the rival circle. Dutch custodian Jaap Stockmann, however, was not unduly troubled by the English shots at the goal.