GreatFire.Org, which operates websites seeking to circumvent China's vast censorship apparatus, pointed to statements by Google, Microsoft and Mozilla as showing the Chinese government was involved in so-called "man-in-the-middle" operations.
Such attacks involve an unauthorised intermediary inserting themselves between computer users and their online destinations, usually undetected, putting them in a position to harvest data traffic, including passwords.
GreatFire.Org said the firms' statements amounted to "concrete evidence" the Cyberspace Administration of China (CAC) authority and the China Internet Network Information Centre (CNNIC) administrator were "behind these malicious actions and are endangering safety and security on the Internet for everyone".
At the same time, Washington and Beijing regularly trade accusations of hacking, with FBI Director James Comey declaring last October that China was at the "top of the list" of countries launching cyberattacks on US firms.
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Beijing has also drawn criticism for a recent draft law that would require foreign companies to hand over their encryption keys and other sensitive data in order to do business in China.
A Google security engineer on Monday posted on the company's online security blog that CNNIC and a firm called MCS Holdings had been found to have issued "unauthorised digital certificates for several Google domains".
"The misissued certificates would be trusted by almost all browsers and operating systems," he wrote, describing the resulting vulnerability as a "serious breach" of the Internet certificate authority system.
Yesterday, Microsoft and Mozilla, owner of the popular Firefox web browser, announced that they were revoking trust in all MCS certificates.
Last week, GreatFire.Org said that it had been hit by a barrage of automated requests known as a distributed denial of service (DDoS) attack in an attempt to bring down its anti-censorship services.