Her death was announced on the official James Bond Twitter account, which read, "We are sad to hear that Molly Peters has passed away at the age of 75. Our thoughts are with her family."
Peters was the first ever Bond girl to strip on-screen and her scenes with Connery had landed the 1965 film in trouble with the British Board of Film Classification (BBFC).
The news of her death comes close on the heels of the passing of Bond star Roger Moore.