The 54-year-old actor, however, was outbid during a silent auction at Sean Penn's annual gala for Haiti, held at Milk Studios in California, reported Variety.
During the charity gala, the auctioneer announced the opportunity to watch an episode with Clarke, who was in attendance at the event, along with her "Game of Thrones" co- star Kit Harington.
The auction to watch the episode with Clarke started at USD 20,000.
Pitt bid USD 80,000 to watch an episode of of the epic fantasy drama with Clarke. Then he outbid himself to USD 90,000. When Harington offered to also sit in on the episode viewing, Pitt raised his own bid to USD 120,000.
The charity event to benefit the J/P HRO & Disaster Relief Organizations, hosted by Penn, CAA's Bryan Lourd and Sean and Alexandra Parker, also honoured Leonardo DiCaprio for his work combating climate change.