Haramardeep Singh Ghuman was killed when his car collided with another car early on the A468 in Caerphilly town on Sunday, Wales Online reported.
Ghulam, from Bridgend, died on the scene, while the driver of the other vehicle was admitted to hospital with serious injuries, according to police.
Gwent Police Area Support Unit Sergeant Robert Ball said: "We are appealing for witnesses to this collision, and I would ask anyone who saw this incident to contact us.