Under an agreement struck last week, Ukrainian forces and Russian-backed separatist rebels are to begin this week pulling back their heavy weaponry to form a wide buffer zone. In a live midnight broadcast, Ukrainian President Petro Poroshenko issued the order for the country's armed forces to hold their fire.
In a statement before issuing that order, Poroshenko expressed concern over risks to the cease-fire posed by the unrest that raged yesterday around the strategic government-held railway hub of Debaltseve, which is besieged by separatist forces.
Shells rained down yesterday afternoon on the government-held town of Artemivsk, 40 kilometres (25 miles) north of Debaltseve, striking a school, which rapidly burned to the ground.
An undated satellite image released yesterday by the Ukrainian government showed a five-kilometre-(three-mile-)long cloud of black smoke hovering above Svitlodarsk, evidence of what it said was the scale of rebel shelling.
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Russia has repeatedly denied repeated Western claims that it has sent troops and equipment to the rebels. But yesterday, the US ambassador to Ukraine, Geoffrey Pyatt, posted on Twitter what he said were satellite photos showing Russian artillery systems near the town of Lomuvatka, 20 kilometres (12 miles) northeast of Debaltseve.
Ahead of the ceasefire deadline, statements by separatist officials cast doubt on whether fighting would end at the appointed hour.
Alexander Zakharchenko, the rebel leader in the city of Donetsk, was quoted by the RIA Novosti news agency as saying his fighters would not allow Ukrainian forces to escape Debaltseve. Separatists have said the Ukrainian troops there would be offered only the opportunity to surrender.
In a telephone call with Poroshenko hours before the start of the ceasefire period, President Barack Obama expressed his "deep concern about the ongoing violence, particularly in and around Debaltseve."