The song, written by composer Alan Menken and Tim Rice, will also be a part of the film's soundtrack.
Portions of the song are performed throughout the film and interpolated into the underscore before Dion's full-length version debuts in the film's custom main-on-end title design.
"Being a part of the original 'Beauty and the Beast' was such a magical experience in my life, and I'm truly honored to be a part of this film again," Dion said in a statement.
"Celine was the unanimous choice of the filmmakers and studio to perform this song. And everyone involved with the film is thrilled she agreed to be part of this new live-action adaptation," Leib said.
Dion originally performed the duet "Beauty and the Beast" - featuring Menken's haunting melody and two-time Oscar-winner Howard Ashman's unforgettable lyrics - with Peabo Bryson for the animated film. The song became an instant classic and went on to win Oscar, Golden Globe and Grammy.
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