Thousands of students took to the streets of Santiago yesterday to condemn President Michelle Bachelet's reforms, claiming they fall short of overhauling a highly unequal education system inherited from the 1973-1990 dictatorship of late ruler Augusto Pinochet.
The protest began in the early morning hours as students dragged piles of rubbish into the streets and set them on fire, blocking traffic.
Demonstrators then massed outside the education ministry and state television network.
"We're still a very long way from achieving our dreams. The reforms are very inadequate," student leader Claudia Arevalo told AFP.
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An art student from Catholic University is currently in critical condition after being knocked to the ground and badly injured by a police water cannon during a protest in the port city of Valparaiso last week.
Police again used water cannons yesterday as masked protesters attacked them with sticks and stones during an unauthorised march through the center of the capital.
A new march was planned for later in the day.
Bachelet won a second term in 2013 with promises to launch an ambitious reform of the education system.
Last week, she announced a bill to provide free university education to 60 per cent of the poorest students starting next year, reaching 70 per cent in 2018 and 100 per cent in 2020.
But her reform push has slowed amid a series of damaging corruption scandals, including one involving her son, that have dented her popularity - currently at 29 per cent, her lowest rating ever.