Chinese companies invested in 7,961 overseas enterprises in 164 countries and regions in the past year, Ministry of Commerce said.
Beijing is also giving a major thrust to Chinese President Xi Jinping's Silk Road initiative.
The Belt and Road (Silk Road) initiative was a strong boost to cooperation between Chinese and foreign firms, state-run Xinhua news agency reported.
Outbound investment to countries involved in the initiative totalled USD 14.53 billion in 2016 Han Yong, an official with the commerce ministry said.
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Up to 18.3 per cent of the ODI went to manufacturing in 2016, up from 12.1 per cent in 2015.
Meanwhile, Chinese companies carried out 197 overseas mergers and acquisitions (M&A) in the manufacturing sector last year, accounting for 26.6 per cent of the total.
In the same period, 12 per cent of China's total ODI was invested in information transmission, software and information technology services, and 109 overseas M&A deals related to the sector were announced by Chinese firms.
Han said overseas M&A had facilitated China's economic restructuring and industrial upgrading.
Chinese regulators are also looking out for potential risks brought by "irrational tendencies" amid rapid outbound investment growth and are examining irregularities in such investments, an official with China's top economic planner said last week.