The group of 15 Rio Olympics gold medallists in cycling, weight-lifting, taekwondo, shooting, women's volley ball, and athletics will share their experiences with their Taiwanese counterparts and students during the five-day visit, organisers said.
The visiting Olympians include Zhang Mengxue, who won China's first gold medal at the Rio Games in women's 10m air pistol, and three players from the women's volleyball team that claimed gold after a 12-year wait.
Beijing has suspended official contacts with Taipei after Tsai's government took office in May, as it fails to publicly accept the "one China" principle which governed ties with her predecessor.
Taiwan has accused China of pressuring a number of countries to deport Taiwanese fraud suspects to China rather than their home territory, and blamed Beijing for blocking it from attending various international events.
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Sports officials hope the visit will help promote exchanges in their fields despite growing political tensions.
Li Yingchuan, a vice president of Chinese Olympic Committee, urged the two sides to continue to work together to promote sports ties and contribute to "deepening the friendship of the people".
"We hope the sports sectors in both sides will jointly treasure the fruits from our exchanges and maintain the existing good situation in sports exchanges," he told a press conference in Taipei.
China still considers the self-ruling island as part of its territory even though they split in 1949 after a civil war.
Taiwan takes part as Chinese Taipei at major events including the Olympics, instead of using its official title the "Republic of China" or its national flag.
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