The daughter of TV presenters Richard Madeley and Judy Finnigan is set to take part in the winter sports reality show, reported Daily Express.
Chloe, 27, has been drafted in to replace 'Strictly Come Dancing' star Ola Jordan, who was forced to pull out of the show due to an injury.
Chloe will now compete against a number of celebrities including former 'The Only Way Is Essex' star Joey Essex, model Heather Mills and ex-professional rugby player Mike Tindall in the winter sports contest, which kicks off in Austria next month.