Expedition 54 Commander Alexander Misurkin and Flight Engineer Anton Shkaplerov of the Russian space agency Roscosmos began the spacewalk at 10.34 am EST (9.04 PM IST), according to a blog post by the US space agency.
They re-entered the airlock and closed the hatch at 6.47 pm EST (5.17 am IST), it said.
During the record-breaking spacewalk, the duo installed a new electronics and telemetry box for the high gain antenna on the Zvezda service module to enhance communications between Russian flight controllers and the Russian modules.
It is the fifth-longest spacewalk in human spaceflight history.