Balakrishnan met the Archbishop at the Bishop's house and held discussions.
"We normally meet prominent persons and exchange views and when an opportunity arose, this meeting with the Archbishop was held," Balakrishnan told reporters after the meeting.
"We had a friendly discussion," he said, adding, LDF maintained cordial relations with everyone.
The Church's stand and needs were made clear by the church leaders and they handed over a letter to Balakrishnan.
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Asked about former Government Chief Whip P C George, who was denied a ticket by the LDF, he said,"CPI(M) was not the enemy of P C George. But his biggest enemy was his tongue," he said.
The meeting with the Archbishop is significant as the party had differences with the Church on certain matters earlier.
The Catholic Church had few years ago written a pastoral letter recommending a "liberation struggle" on the lines of the one in 1950's to liberate the education sector in Kerala from the state control to enable private managements charge fees and capitation fees without government's intervention.
Vijayan had also in 2007 called Thamarassery Bishop a "wretched creature".