The 44-year-old actor's sharp suits in the James Bond movies helped him top the poll for Lovefilm, and Smith's "Men in Black" agent alter-ego landed him second place, reported Daily Star.
Late star Heath Ledger came third for his eccentric Joker character in "The Dark Knight", Depp was placed fourth for his turn in "Charlie and the Chocolate Factory", while Jim Carrey's outlandish outfits in "Dumb and Dumber" placed him into fifth.