Laggards last season, Delhi and Punjab had hoped for a positive start but both the teams suffered contrasting defeats at the hands of Kolkata Knight Riders and Gujarat Lions respectively.
Delhi had finished 7th in the 2015 edition and they would be looking to get their combination right to get into the winning mode.
The Daredevils, who had qualified for Champions League T20 twice, have a new unit with current India U-19 coach and batting great Rahul Dravid as their mentor and Paddy Upton as their coach.
Against Kolkata, Delhi cut a sorry figure when they were dismissed for 98 in 17.4 overs with only four of their batsmen reaching double figures and Zaheer has to ensure that they come up with a better performance tomorrow.
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A lot was expected from Carlos Brathwaite, who became the toast of the cricketing world after hitting England's Ben Stokes for four consecutive sixes to win the ICC World T20 final for the West Indies.
But the strapping youngster could not make much impact against Kolkata and Delhi will expect him to repeat his World T20 exploits.
Delhi's batting unit looks weak with only Quinton de Kock (17) and Sanju Samson (15) making the double figures among the top five batsmen. Comparatively, their bowling unit looks more solid with the presence of Nathan Counter-Nile, Chris Morris and Amit Mishra, besides Zaheer himself.
At 37, Zaheer has been handed the responsibility of guiding a young side and he would like to lead by example.
Despite Delhi's loss, the Mumbaikar defended his young team and sounded optimistic about the times to come.
(REOPENS DEL 16)
On the other hand, Kings XI Punjab, who have been the runner-up and semi-finalists in the past IPLs, were equally lacklustre as they finished at the bottom of the table last year.
The side did not add any significant player this season, and their star player Virender Sehwag has also retired. They have a new captain in South Africa's David Miller in place of Australian George Bailey, who is no more with the team.
However, the team failed to defend the total after their bowlers were taken to the cleaners by Aaron Finch and Dinesh Karthik.
Sandeep Sharma, Mitchell Johnson and Mohit Sharma constitute their pace battery, while Australia's Marcus Stoinis, Axar Patel and Pardeep Sahu make the spin department and they will have to come good for Punjab to have any chance tomorrow.
Delhi Daredevils: Zaheer Khan (c), Quinton de Kock, JP Duminy, Mayank Agarwal, Shreyas Iyer, Carlos Brathwaite, Karun Nair, Pawan Negi, Rishabh Pant, Sanju Samson, Pawan Suyal, Jayant Yadav, Chris Morris, Sam Billings, Nathan Coulter-Nile, Imran Tahir, Mahipal Lomor, Chama Milind, Amit Mishra, Mohammed Shami, Shahbaz Nadeem, Khaleel Ahmed, Akhil Herwadkar, Pratyush Singh.
Kings XI Punjab: David Miller (Capt.), Kyle Abbott, Murali Vijay, Manan Vohra, Mitchell Johnson, Shaun Marsh, Glenn Maxwell, Anureet Singh, Axar Patel, Wriddhiman Saha (wk), Pardeep Sahu, Sandeep Sharma, Mohit Sharma, Marcus Stoinis, Swapnil Singh, Armaan Jaffer, Farhaan Behardien, KC Cariappa, Rishi Dhawan, Gurkeerat Singh Mann, Nikhil Naik, Shardul Thakur.