Around a dozen experts arrived in a convoy of cars but were not permitted to enter the zone where the Malaysia Airlines plane crashed in July, killing 298 people, in remote rebel-held territory east of Donetsk.
The Dutch team hopes to begin work as soon as possible but there are concerns that rebels could be gearing up for a fresh offensive despite a shaky ceasefire signed in September but dogged by localised outbreaks of fighting.
There has been intense shelling around Donetsk in recent days and an AFP journalist saw 28 trucks, six tanks and 14 howitzer artillery systems and two armoured personnel carriers driving through rebel territory around the city Monday.
"We hope that the removal of debris can start as soon as possile but that depends on the situation on the ground," Wim van der Wegen, a spokesman for the Dutch Safety Board, told AFP.
Pieter-Jaap Aalbersberg, the head of the recovery mission, told public television in the Netherlands that the team was "absolutely ready" to start collecting debris.
The delay came as Russian President Vladimir Putin, facing a fraught week of diplomacy with the West, discussed Ukraine with US President Barack Obama and Australian Prime Minister Tony Abbott at the Asia Pacific Economic Cooperation (APEC) summit in Beijing.
Ukraine and the West accuse Russia of supplying the pro-Kremlin separatists with the missile that shot down the plane, while Moscow and the rebels have pointed the finger of blame at Kiev's forces.
The talks with Obama came after US Vice President Joe Biden warned Monday after a call with Ukraine's President Petro Poroshenko that the "costs to Russia will increase" if it continues to "wilfully violate" the terms of a ceasefire signed in September.
Putin has denied that rebels are hindering access to the site, blaming Ukrainian forces for shelling the area.
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