Vincent, who has already confessed to fixing and has been under investigation by the ICC's Anti-Corruption and Security Unit, and Arif, a Pakistani living in England, are being charged with more than 15 counts of match-fixing, according to a report in 'Daily Telegraph'.
If the players are found guilty, they face lifetime bans from the sport, and the 40-over match between Sussex and Kent played at Hove in August 2011 will be the first proven case of the result of a county match being fixed, the report said.
Arif faces at least five counts relating to the Sussex game versus Kent alone.
The charges, which are being issued by the ECB, rather than the ICC, came just days after Vincent had given anti-corruption detectives a wealth of detail about fixing across the cricketing world. MORE PTI
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The former international "has agreed a plea bargain in the hope of avoiding a criminal prosecution for his involvement in and knowledge of spot-fixing in five or more countries" between 2008-2012.
There were suspicions at the time the match was corrupt but it was cleared by the ICC's anti-corruption unit following an investigation by its analysts which failed to uncover any wrongdoing.
"It is embarrassing for the under-fire ICC anti-corruption unit that its own officers gave a clean bill of health to a match which is now going to be the subject of a high profile fixing case," the report said.
The 32-year-old Arif was born in Pakistan and qualified as a non-overseas player for Sussex through his wife's Danish passport.