Rihanna and Drake will collaborate on 'The Monster', taken from Slim Shady's album The Marshall Mathers LP2, and they will perform an exciting rendition of the track on Sunday night, reported Daily Mirror.
The track is not the first time the pair have recorded together, having previously worked on two versions of huge hit 'Love The Way You Lie'.
Aside from this powerhouse duo, Ellie Goulding and Zedd are also set to sing at the event. The 2014 MTV Movie Awards will be hosted by Conan O'Brien at the Los Angeles' Nokia Theater on April 13.