India had begun the day at 319 for four.
Haseeb Hameed (62) and Alastair Cook (46) will resume England's second innings tomorrow.
Brief Scores:
England: 537 and 114 without loss in 37 overs.(H Hameed 62 batting, A Cook 46 batting).
India 1st innings: 488 all out in 162 overs (Murali Vijay 126, Cheteshwar Pujara 124, R Ashwin 70, Virat Kohli 40; Adil Rashid 4/114).