Mogherini also held delegation-level talks with Minister of State for External Affairs M J Akbar during which they discussed progress on decisions taken during the annual summit in Brussels last year.
Mogherini is here on a two-day visit.
In the meeting, the EU side is understood to have pushed for early resumption of talks for the long-pending free trade pact between India and the EU.
The EU has been pressing India to extend by six months its bilateral investment pacts with several EU-member countries which are expiring soon, saying absence of the treaties could adversely impact trade ties and FTA talks.
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India's existing trade and investment pacts with the Netherlands came to an end in November while similar pacts with several other EU countries are expiring in the coming months.
The BTIA talks have been stalled since May 2013 when both sides failed to bridge substantial gaps on issues like data security status for the IT sector.
Launched in June 2007, negotiations for the proposed agreement have witnessed many hurdles as both sides have major differences on crucial issues.
In the last EU-India Summit in Brussels, the two sides had failed to make any announcement on resumption of the negotiations as many bottlenecks still remained.
Besides demanding significant duty cuts in automobiles, the EU wants tax reduction in wines, spirits and dairy products, and a strong intellectual property regime.
On the other hand, India is asking the EU to grant it 'data secure nation' status. The country is among nations not considered data secure by the EU.
The matter is crucial as it will have a bearing on Indian IT companies wanting market access.
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