"Not much has happened since the visit of the Ukrainian president at the last summit in June", German Chancellor Angela Merkel said as she arrived for a new meeting of EU leaders to discuss Ukraine as well as fill top EU posts.
"We will talk about new sanctions because we think that the Russian contribution for peace in Ukraine is not sufficient," she added.
According to a draft summit statement seen by AFP, new steps could include freezing programmes in Russia run by the EU's European Investment Bank as well as a request that the European Bank of Reconstruction and Development halt its own work in the country.
"What is expected is a certain escalation of sanctions but that does not reach Phase 3," said French Foreign Minister Laurent Fabius, referring to the EU term for sanctions that would target entire sectors of the Russian economy.
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"We must at the same time show resolve and maintain dialogue," Fabius added.
The move in Brussels comes amid increasing frustration in Washington towards the EU's cautious approach.
The United States has hinted it is preparing to adopt its own punitive steps against Russia's defence and financial sectors.
Germany and France have been spearheading EU efforts to revive a Ukrainian truce in the hope more sanctions against Russia could be avoided.
Earlier today, Merkel's office said she and Ukrainian President Petro Poroshenko had agreed by phone that "Russia has been insufficient in meeting expectations" on steps to end Ukraine's worst crisis since its independence from Moscow in 1991.
"The situation in Ukraine is unacceptable. We need to send a very clear message with clear actions," said British Prime Minister David Cameron, arriving for the talks.