Security forces fired tear gas to disperse fighting fans for a third day in a row, just hours before the match which is one of five Euro games classed as high-risk for hooliganism.
"Police intervened in a clash between English, Russian and French supporters in the Vieux-Port district," said local police chief Laurent Nunez.
Meanwhile, three England fans and a French woman were to appear in court today charged with acts of violence in Marseille, the state prosecutor's office said.
One of the three English nationals picked up is a minor and will appear before a juvenile judge.
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A Frenchman arrested for violence and theft with violence on Thursday appeared before a judge earlier today.
Police made a total of seven arrests during the clashes last night, which ended with hundreds of boozed-up and bare- chested fans stood, beer glasses in hand, staring down French riot police.
French police have offered to escort England fans to the match for their own safety.