The four men, of whom two are still working at the Fukushima Daiichi plant, will demand the companies pay a total of 65 million yen ($620,000), mostly in hazard allowances.
The workers, whose ages range from those in their 30s to their 60s, say they have not been properly compensated for the risks their work entails, including removing contaminated debris and patrolling at the plant.
The suit will be filed with the Iwaki branch of the Fukushima District Court tomorrow, according to lawyer Tsuguo Hirota.
"My health may be harmed some day... I believe there are many people who can't speak out about this kind of (underpaying) problem," one of the workers told public broadcaster NHK.
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"I may get fired or may be given no further work. But I hope people will take this as an opportunity to speak up and get paid," he said.
A massive tsunami triggered by a 9.0-magnitude earthquake in March 2011 smashed into the plant on Japan's northeastern coast, sending reactors into meltdown and contaminating a wide area.
Of the 6,000 people working at the plant every day over the last two months, only a handful were directly employed by TEPCO. Allegations continue to swirl that organised crime has had a hand in staffing subcontractors at the bottom of the food chain.
The sometimes murky arrangements mean that despite pledges by TEPCO of extra cash for employees, it is often difficult to tell if the money filters through to the people at the sharp end, or is skimmed off at one of the many intermediary levels.