The ministers will gather in Brussels for their last meeting before the summer break. International Monetary Fund chief Christine Lagarde is also expected to attend.
Top on the agenda is a progress report drawn up by Greece's so-called troika of international creditors -- the European Union, the European Central Bank and the IMF -- which will detail if Athens is indeed undertaking reforms pledged in exchange for rescue funds.
The funds are necessary as Greece needs to redeem bonds worth 6.6 billion euros by mid-August.
Today, Greek officials said they were close to a deal with the three creditors over a new package of reforms required in exchange for the aid, including thousands of job cuts in the public sector.
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The marathon talks moved from Athens to Brussels today, and are expected to go on to the last minute before the Eurogroup meeting is due to open.
Athens had pledged to axe 4,000 state jobs by the end of the year, as well as redeploy 25,000 civil servants across its vast bureaucracy.
Eurogroup ministers are also due to discuss the situation in another bailed-out country -- Portugal, which sunk into a political crisis over the shock resignations of two key ministers this month.
"Portugal respects all of its engagements and has not asked for anything," said a European diplomat ahead of the meeting.