Hathaway is going to take the stage at Joe's Pub at The Public in New York and perform songs from Broadway hit musical "Cabaret", reported Aceshowbiz.
The 29-year-old actress, who will also serve as a host, will be joined by a number of special guests from stage and screen at the event on October 24.
She will play renditions of John Kander and Fred Ebb's famous songs, including "Willkommen", "Cabaret", "Maybe This Time" and "Perfectly Marvelous".
The gig is conducted to celebrate and support revitalization of Public Theater's downtown home at Astor Place.
The evening will feature direction by Tony Award winner, Ted Sperling, and musical direction by Mary-Mitchell Campbell.
"I am delighted to reunite with The Public for this special night to celebrate the theater's rededication, and support its mission to spread great theater to all the people of New York (tourists are welcome too)," Hathaway said in a statement.