The Victoria's Secret star has been shot by iconic photographer Ranking for the charity organisation Children in Need's inaugural BearFaced campaign, which takes its name from the BBC charity's yellow teddy mascot Pudsey, reported Us magazine.
The photo shows the fresh-faced Klum, 39, with her hair pulled back and a single, tiny paw print on her cheek.
The campaign will be launched on November 12 in an effort to encourage women to go without make-up to help raise money.
"I am so proud to be taking part in this year's BBC Children in Need BearFaced campaign. Having worked in the fashion industry for a number of years, I am a firm believer of encouraging women's empowerment. And what better way to do so than supporting such a fantastic charity," said Klum.