Hiddleston won the trophy for his role in "The Night Manager" and as he was speaking to the camera, Hemsworth walked into the shot and grabbed the trophy from his co-star.
"Oh, is that for us? For Home and Away, yeah? All the work I did on (it)... Thanks to everyone on Channel Seven. I loved working on Home and Away," Hemsworth said in the video carried by Nine News.
Hemsworth continued to talk about his show but did praise Hiddleston's show.
"Home and Away rocks! And so does The Night Manager," he said, patting the award winner on the shoulder.
Hiddleston signed off saying, "Ok, I guess I'll leave it there.