The pair originally met on the set of 2005 movie "Mr & Mrs Smith" and have teamed up once again on the upcoming drama.
The film is also directed by Jolie, but Pitt insists she did not let him off the hook if he failed to deliver on any scenes, reported Female First.
"Angelina knows very well, what she wants and I don't get any special treatment on set. As an actor you need a good relationship to the filmmaker to trust blindly and let yourself fall into it. We know each other so well, just one gaze from her and I know, I messed up this scene," he said.