Rahane (108 not out) carved out his seventh Test hundred to strengthen India's hold on the game as the visitors declared their innings at 500 for nine in response to West Indies' first innings score of 196.
Rahane's gritty century was followed by the declaration in the post lunch session but intermittent rain ensured not a single ball was bowled for the remainder of the day.
The pacers were brought on almost immediately to block any plans of quick scoring on part of the batsmen. Even so, the 450-mark came up in the 161st over, as also the 250-lead. Thereafter, rain started pouring in. There is threat of tropical storm Earl still looming large on the match.
After an hour, the game restarted with just about 25 minutes to play until tea. In this interim, West Indies got a couple of quick wickets, as Roston Chase (5-121) removed Mishra, caught at short leg, before sending back Mohammed Shami (0) first ball. Umesh Yadav denied Chase a hat trick, even as Rahane tried to speed up to his hundred, smacking Chase for a six.
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India declared their innings thereafter, leaving about 40 minutes for the West Indies to play out before the close of the day, but rain intervened again and an early tea was taken.
Earlier in the day, the hosts had come out firing even as Jason Holder (1-72) troubled both Rahane and Wriddhiman Saha (47).