Netherlands took the lead in the 36th minute through a penalty corner conversion by Mink van der Weerden before Mirco Pruijser (43rd) and Roel Bovendeert (54th) scored two field goals. India's lone goal came from the sticks of Chinglensana Singh in the 47th minute.
On the eve of the match, India's chief coach Roelant Oltmans had said that the hosts would have to do away with their inconsistent show if they want to progress in world hockey but his words hardly had any impact on his side as they produced another lacklustre performance to slump to their second loss in the eight-nation tournament
The Netherlands, meanwhile, have topped Pool B with seven points out of two wins and a draw and will play the bottom placed team of Pool A.
By virtue of this win, the Netherlands have also managed to avenge their 2-3 loss against India during the pool matches of Champions Trophy in Bhubaneshwar last year.
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After a disappointing tournament opener against Argentina, India produced an inspired show to hold Olympic champions Germany to a 1-1 draw and soon after the match Oltmans called his wards to play consistent hockey.
The Indians had just 36 per cent ball possession as against their rivals' 64. The hosts managed just eight shots at the goal while Netherlands had 18 to their credit, a grim reality about India's inconsistent showing.
(REOPENS FGN 24)
Seasoned Indian midfielder Sardar Singh was again in the picture as India increased the lead in the 23rd minute as he worked up on the right flank and put Ramandeep Singh in possession on top of the circle.
Under pressure, Pakistan responded by forcing their first penalty corner, which was converted by Muhammad Aleem Bilal in the 26th minute. Bilal sounded the boards with a low drag-flick that beat the goalkeeper.
Pakistan defence had no trouble in warding away India's attempts to send long diagonal balls into the circle and capitalised on a lapse by the Indian defence to draw 2-2 parity in the 38th minute. Ali Shan wasted no time in slapping the ball that had got deflected to him inside the scoring zone.
India wrested the lead back in the 51st minute when Sardar again shaped the goal-bearing move by working his way up on the left flank and gave a through pass to Thimmaiah, who beat Pakistan custodian Fareed Ahmed with a diagonal flick that ended inside the right goal-post.
Pakistan forced their second penalty corner in the 53rd minute, but the opportunity went abegging as the push could not be stopped.