Aravindan Balakrishnan is charged with 25 offences including false imprisonment, cruelty to a person under 16 years, indecent assault and rape.
He will appear before Westminster Magistrates' Court on December 17.
Balakrishnan is accused of imprisoning three women in a house in south London between 1983 and 2013 which came to light last year.
"After careful consideration, we have decided that there is sufficient evidence for a realistic prospect of conviction and that a prosecution is in the public interest," said Anthony Connell, senior prosecutor at the Crown Prosecution Service (CPS).
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Pattni was released with no further action earlier this year when prosecutors decided there was "insufficient evidence for a realistic prospect of conviction".
"May I remind all concerned that criminal proceedings against the defendant have been commenced and of his right to a fair trial. It is extremely important that there should be no reporting, commentary or sharing of information online which could in any way prejudice these proceedings," the CPS warned in reference to reporting restrictions which are now in place.