England's semifinal victory over Spain, coming after the Netherlands' win over Germany in the other semifinal in the European Championships freed one quota place as both the finalists have already qualified for the Olympic Games.
India took the quota place on the basis of its fifth-place finish in the women's Hockey World League Semifinals in Antwerp, Belgium last month.
International Hockey Federation (FIH) confirmed that Indian women's team has qualified for the Rio Games.
"The winner of the EuroHockey Championships will qualify for the 2016 Olympics as European continental champions, opening up a further qualification spot which India secure as the team who ranked highest at the Hockey World League Semi-Finals not already qualified," it said.
Indian women's team now join nine other teams, who have already qualified for 2016 Rio Games -- Korea as Asian Games champions, Argentina as Pan Am Games champions and Great Britain, China, Germany, Netherlands, Australia, New Zealand and the USA through the Hockey World League Semi-Finals.