Accompanied by a guitarist, the singer shows of her vocal talents by rapping and singing without a microphone, reported Digital Spy.
'Ain't Been Done' is featured on the singer's third studio album Sweet Talker, which also features singles 'Bang Bang' and 'Burning Up'.
Jessie recently admitted that she was 'soft' on her 2013 sophomore album Alive.
When asked if she had to rein it in at all for Sweet Talker, the singer said she didn't and decided to "let go".
"But I definitely feel like I tried to soften myself on the second album and listening back to it now - I love the album, I think it's really good still - but I just don't think there's enough soul in it and I wanted to get that back," she added.
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