Jolie, 39, beat, Cameron Diaz ("Annie"), Donald Sutherland ("The Hunger Games"), Jamie Foxx ("The Amazing Spider-Man 2"), Lee Pace ("Guardians of the Galaxy") and Meryl Streep ("Into The Woods") to receive the award.
The actress was also the executive produce of the movie.
Nick Jonas, who hosted the event, has won the best singer (male) award and Selena Gomez bagged the best female singer trophy, said The Hollywood Reporter.
"Dance Moms" has been declared the favourite reality show, while "The Voice" has got the honour of the favourite talent competition show.
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Oscar-winning movie "Big Hero 6" received the best animated film award. Jennifer Lawrence has become the best female action star, while the best male action star award went to Liam Hemsowrth.
Ben Stiller has bagged the favourite movie actor and Emma Stone has won the favourite movie actress trophy.
Lawrence's "The Hunger Games: Mockingjay - Part 1" has been declared the favourite movie.
Ross Lync has got the best TV actor award and Laura Marano has won the best TV actress.