Brolin and Lane were married in 2004. It was the second marriage for both, reported Aceshowbiz.
"It was a mutual decision. It is very amicable. It's not ugly, it's just over," a representative of the couple said.
Brolin was recently arrested for public intoxication just before midnight during a 2013 New Year celebration. He was let go without charge.
According to reports, he was spotted without his wedding ring the next day when grabbing a bite with a male companion at Sauce on Hampton in Venice, Calif.
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Brolin was previously married to actress Alice Adair and got divorced in 1994. They have two children, 18-year-old daughter Eden and 24-year-old son Trevor.
Lane was previously married to actor Christopher Lambert and also called it quits in 1994. They have 19-year-old daughter Eleanor.