The 39-year-old catwalk queen is due to style her very first shoot for the magazine as part of the forthcoming Spring issue and will work closely with the rest of the fashion team to choose photographers and models, reported Contactmusic.
This marks the first time Moss, who has covered the British style bible 33 times since her first shoot in March 1993, will take part in the creative process behind the camera.
"I am absolutely delighted that Kate is going to work with us in this new role. Her undoubtedly brilliant sense of style, depth of fashion knowledge and understanding of what makes a wonderful image will be exciting to see on the pages of British Vogue. I am really looking forward to working with her on ideas," Alexandra Shulman, British Vogue's Editor-in-Chief, said.