The Nathan Chapman-co-produced ballad, about Urban offering his loved one a shoulder to cry on, premiered on October 19, reported Aceshowbiz.
"Break on me/ Shatter like glass, come apart in my hands/ Take as long as it takes, girl," he tells the heartbroken lady on the guitar-driven track.
"Break on me/ Put your head on my chest, let me help you forget/ When your heart needs to break, just break on me."
The song was written by Ross Copperman and Jon Nite.
The "American Idol" judge's new album has also spawned "John Cougar, John Deere, John 3:16", which came out a few weeks ago.
No exact release date for the follow-up to 2013's "Fuse" has been set.