The 31-year-old, who gave birth to her first child, North West, with partner Kanye West, made the revelation in scenes filmed for the upcoming series of 'Keeping Up with the Kardashians', reported Contactmusic.
"As soon as I pop this thing out, I want to do Playboy or some nude shoot," she said.
Kim, who posed for the magazine in 2007, previously blasted the publication for posting the photographs online in 2010, once she became famous.
However, she has also claimed her decision to appear in Playboy was to cement her independence.