Lokayukta Justice (retd) M L Tahiliani administered the oath of office to Kshatriya at Sahyadri state guest house in Mumbai.
State Chief Information Commissioner Ratnakar Gaikwad, former CIC Suresh Joshi and some of the state's top bureaucrats were present on the occasion.
Kshatriya's tenure will be of five years. He retired as Chief Secretary of Maharashtra yesterday.
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RTS, formed through a state legislation, is entrusted
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with the task of overseeing delivery of various government services to the people.
"My job will be to oversee implementation of the Act while working with district collectors and divisional commissioners, and setting up a system to ensure that citizens benefit from the Act," he said.