Rimes and Cibrian has signed a deal with VH1 for the show, which will provide a glimpse into their lives, reported Contactmusic.
"We are really excited to be working together on a unique show that will give you a glimpse into who we really are or better yet, who we're really not," the couple said in a joint statement.
"We're thrilled to partner with VH1 and The Gurneys to put our spin on a project full of love, humour and music," they added.
Both were married at the time, Cibrian to reality TV star Brandi Glanville and Rimes to dancer Dean Sheremet, but have since split from their respective partners and wed in 2011.
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