DiCaprio's Appian Way will develop fact-based projects with topical and provocative environmental and conservation themes, reported Aceshowbiz.
"Working with Netflix on 'Virunga' has sparked a shared vision about projects that we want to develop and bring to viewers," said DiCaprio.
"There's never been a more critical time for our planet or more of a need for gifted storytellers to help us all make sense of the issues we face. Through this partnership with Netflix, I hope to give documentary filmmakers doing urgent and important work the chance to have their films seen immediately by audiences all around the world."
DiCaprio, 40, will be the producer or executive producer for all the films and docu-series launched under the deal.